N-(Pyrazin-2-yl)-4-toluidine

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N-(Pyrazin-2-yl)-4-toluidine

The two aromatic systems in the title compound, C(11)H(11)N(3), are inclined by 19.1 (1)°, whilst the angle at the central amino N atom is 130.3 (2)°. The amino group forms a hydrogen bond to the pyrazine N-4 atom of an adjacent mol-ecule, forming a chain motif.

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4-Chloro-N-(pyrazin-2-yl)aniline

In the title compound, C(10)H(8)ClN(3), the dihedral angle between the aromatic rings is 43.0 (1)° and the bridging C-N-C angle is 128.19 (16)°. The amino N atom of one mol-ecule forms a hydrogen bond to the 1-N atom of an adjacent pyrazinyl ring, generating an inversion dimer.

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N-(Quinoxalin-2-yl)-4-toluidine

The aromatic and the aromatic fused-rings in the title compound, C(15)H(13)N(3), open the angle at the planar N atom to 130.07 (13) and 129.98 (13)° in the two independent mol-ecules in the asymmetric unit. The amino N atom of one mol-ecule forms a hydrogen bond to the 4-N atom of an adjacent quinoxalinyl ring, generating a supra-molecular chain.

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N-(Pyrazin-2-yl)aniline

The two aromatic rings in the title compound, C(10)H(9)N(3), are inclined at 15.2 (1)° to each other; this opens up the angle at the amino N atom to 130.4 (1)°. The amino N atom forms a hydrogen bond to the 4-N atom of an adjacent mol-ecule to create a chain motif.

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2-(4-Bromo­phen­yl)-N-(pyrazin-2-yl)acetamide

In the title compound, C12H10BrN3O, the dihedral angle between the mean planes of the 4-bromo-phenyl and pyrazin-2-yl rings is 54.6 (3)°. An intra-molecular C-H⋯O hydrogen bond generates an S(6) graph-set motif. In the crystal, weak N-H⋯N hydrogen bonds link the mol-ecules into chains along [100]. The chains are linked via C-H⋯N and C-H⋯O hydrogen bonds, forming two-dimensional networks lying p...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s160053680803729x